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hydrogel crystals

Hydrogel water crystals to beat drought

This is a product that goes by many different names: Polyter, Water Crystals, Orbeez, Watergel, Hydrogel, Hydrosource, Water drops, root watering crystals, super-absorbent polymers, PAM, water retention granules, hydrating crystals, water beads, water pebbles, hydrobeads, crystal soil, water jelly, jelly balls, soil moist, super slusher… The list seems endless and shows how much hope is set into this special product.

The only certainty about this topic is that we seem on the verge of a revolutionary breakthrough! Seemingly risk-free, these preparations in pellet or powder form promise wonders regarding water management. They’re said to help watering your pots on the balcony and help for large-scale agriculture. But truth be said, little is known about the long-term effects of hydrogels on soil, plant life, and animal life – us humans included!

Different types of hydrogel to grow plants

Even before modern science explored industrial manners of increasing water retention in soils, agriculturists were hoping to find ways to reduce runoff and make rainwater “stay there” for crops to use. There’s many different forms of irrigation, and modern hydrogels are assuredly the most recent development to date.

However, there are actually many different types of hydrogels. Let’s try to make sense of them.

One single word is the key to all of them: polymer!

But the devil is in the details, and not all polymers are as good as they sound…

What is a superabsorbent polymer?

All living things, from a material point of view, are built up from atoms that are associated to form molecules.

Many molecules are small – think “H20” for water here – but some are quite large, like the DNA that holds a transcript of most of our genes. Quite often, the larger molecules are actually a repetition of many smaller molecules, each dubbed a “monomer” that connect to form one long chain, the “polymer”.

A superabsorbent polymer is such a polymer that is special in how it reacts to water. It has the peculiar trait of having two very different states or shapes:

  • when the surrounding environment is wet, the superabsorbent polymer will attract water molecules and wrap them around itself. It swells depending on how much water it can absorb.
  • when it gets dry, the polymer will release the water and slowly bunch up. It returns to its original, dry, smaller, harder form.

These superabsorbent polymers, or hydrogels, are specifically designed to retain and release water in the hope of helping plants cope with irregular rain or irrigation.

Three major groups of hydrogels

Hydrogel material is always one of the following three major groups:

  • natural hydrogel – this is derived from starch, extracted from crops such as corn and wheat. Often used in processed foods to influence structure.
  • cellulose hydrogel – this comes from plant materials that contain cellulose. Usually mixed in with a small portion of petroleum-based products. Often used in health applications and cosmetics.
  • synthetic hydrogel – 100% derived from petroleum (oil). Currently the cheapest available product category. This type is most often used in agriculture and horticulture.

Here are the differences among hydrogel polymers

  • Polyacrylate vs polyacrylamide (or polyacrylamine)
  • Sodium acrylates vs Potassium polyacrylates
  • Cationic vs Anionic vs Neutral
  • Natural or Biopolymer vs Synthetic
  • Quality grade: Cosmetic, Food and Agricultural grade
  • Manufacturing trust levels

Claims, facts and advantages of hydrogel

Hydrogel, miniature water cisterns in the soil

Hoarding water and releasing it slowly to plants around it is the primary claim that hydrogel manufacturers put forward.

A hydrogel, or superabsorbent polymer, is characterized by either of the following two metrics:

  • how many times it can absorb its own weight in water
  • how much it swells compared to its original, dry size.

For example, the children’s toy Orbeez ® claims it swells over 150 times the original size of the pellet.

A special cellulose-based hydrogel called Polyter ® claims it can absorb up to 500 times its initial weight in water.

Special polymers developed in laboratories reach ratios of up to 1,500! Such a capacity to retain water explains why they’re usually used in small amounts in agricultural applications. Usually, only a couple pounds or kg is enough for an entire field.

Theoretically, it should be possible to design water-absorbing polymers in such a way as to make it possible to never need to irrigate at all. All that’s needed is at least one day of natural rainfall in the year. All the water on that single day of rainfall could be absorbed by the hydrogel embedded in the soil. As time passes, it would slowly be released to the plants around it.

Hydrogel makes space for roots

Since they swell and shrink with each water cycle, the water crystals push the soil around them away and provide small crevices.

  • In soils that are compacted, heavy clay soils, or in passageways where people always tread, this can be precious. Small nooks and passages help plants that have trouble developing a root system.
  • This also increases air circulation. Bacterial and insect life is enhanced. Worms reappear.

Furthermore, this is particularly relevant when soils have been depleted of plant and animal life. Normally, worms and a bugs bore tunnels as they hunt and forage underground. However, in contaminated, dead soil, they’re absent and the ground stays packed. Hydrogel compounds are a solution to make plant recovery easier.

Hydrogel reduces runoff, erosion and evaporation

When gallons and liters of water pour down from the sky, usually only a fraction of it is absorbed by bare soil.

Most of it pools together and runs off, forming rivulets that drag away nutrients and smaller sediments. Soil is left bare and isn’t very nourishing. This is called erosion.

Since a single gallon of superabsorbent material can absorb hundreds or even a thousand gallons of water, much if not all of the water is captured on-site. It won’t collect to run off.

Water isn’t lost to evaporation since it’s held back in the crystals.

Hydrogel and roots fuse to form osmotic nodes

Roots have a gift in that they always find their way towards water. It has been observed that roots will always locate and colonize pellets or crystals saturated with water.

They’ll even grow in and around it to maximize surface contact, forming curious nodes that aren’t so common in the natural world.

The water retention of the hydrogel slush is high enough to prevent loss through evaporation, but not too high that roots can’t pull the water out. This makes it a great medium for the plants to grow.

Hydrogel can dispense needed nutrients or chemicals

When pre-loaded upon manufacturing, hydrogels can be infused with chemicals.

  • Fertilizer, nutrients and even herbicides can be embedded in the polymer.

As water cycles in and out of the chain-like structure, some of these chemicals are leached out to the environment.

This confers precious properties to the hydrogels. Often it is used for good purposes, like Polyter, which adds organic fertilizer compounds to its cellulose-based polymer structure.

At other times, it’s used to spread poison, such as when Monsanto, recently acquired by Bayer, integrated synthetic polyacrylamides (a type of hydrogel made from petroleum) to herbicides. This ensured that the herbicide would stay put and take years to leach out into the ground, sterilizing land or killing off wild flora.

Safety, risks and dangers associated to hydrogel

Hydrogels in agriculture are very recent developments. There isn’t much research on the various dangers that might result from using superabsorbent chemicals over extended periods.

An in-depth review of hydrogel risks that have been considered:

  • presence of acrylamine monomers in small amounts upon purchase – although harmless when multiple acrylamine polymers are bound together, single monomers have been found to foster cancer.
  • slow release of acrylamine monomers as the product degrades – the polymer breaks down over time into its constituent monomers, but some types have been shown to interfere with reproductive hormones. Even if each molecule is broken down by microbes within at most two months, constant exposure may have an effect.
  • Some agricultural water-absorbing crystals release sodium (salt) as they break down, eventually causing salinization.
  • new chemicals used aren’t perfectly characterized – as with many experimental products, potential issues haven’t yet been extensively researched.
  • physical swelling of hydrocrystals may plug or block intestinal tracts of animals and insects when ingested.
  • many hydrogel products are produced in places that don’t have stringent environmental guidelines and industrial practices. Sometimes what is in the bag isn’t what is advertised.

Guaranteed wholesome alternatives

One particular study sought to clarify the importance of natural, organic soil amendments compared to hydrogel water crystals.

The conclusion was rather surprising: although using both manure and hydrogel did produce the highest results, pure manure came in a very close second.

The most advanced solutions such as Polyter strive to rely as much as possible on organic, natural materials. However, they’re still compelled to include some amounts of potassium polyacrylate. Even potassium polyacrylate may prove harmful to some degree, although it’s already much safer than sodium polyacrylate or other additives.

Why take unknown risks when proven solutions already work?

Great organic, healthy solutions to provide sufficient water and nutrients for your plants are already within reach.

  • Mulch – the perfect solution, especially plant-based mulch like flax or pine bark mulch
  • Compost – for nutrients, moisture and microbial life, this is unquestionably the best
  • Ramial Chipped Wood – a revolutionary use for what is normally considered waste by the forest industry
  • Peat – a great soil amendment that doesn’t have any negative impact where it’s used, although harvesting it isn’t yet fully sustainable. New sustainable products are as effective and can now be found in horticulture stores everywhere.

Along with ancient and modern irrigation solutions, this ensures that the soil in our gardens will stay as healthy as nature has intended it to be!

Hydrogel crystals are a revolutionary way of dealing with water stress in the garden. Promising to eliminate watering altogether, this technology is useful.

Can Hydrogel Crystals be used as a Drug Delivery System?

Investigator should not ingest the crystals or drink the liquids associated with the activity. The crystals used in the project are extremely slippery when spilled. Never flush or pour these crystals down the drain, crystal swelling could possibly clog drainpipes. Leave to brew overnight. Also, care should be exercised when handling the hot water and the hot tea brew that will be used in this project.

The supervising adult should discuss the warnings and safety information with the child or children before commencing the activity.

Material Availability

The materials required for this project are readily available and inexpensive.

Approximate Time Required to Complete the Project

1½ hours to complete the activity once the materials are secured and setup. Also between 1 and 2 hours to prepare the Tri-fold board display.

A drug delivery system is a medium or carrier of drugs and medicines to where they are needed in a patient’s body. Medical researchers are currently exploring if it is possible to use hydrogel crystals as possible delivery systems. The research aspect of this science fair project is to determine which of two chemical agents can be used to release the drug (tea) from hydrogel crystals.

Hydrogel superabsorbent crystals, several tea bags, a bag of 8 oz clear plastic cups, table sugar, table salt, sieve (the plastic ones used for sifting flour), distilled water, plastic table spoons, tea pot, measuring cup, and paper towels. With the possible exception of the crystals, all the other items can be purchased from the local supermarket and garden supply store. Also, a Tri-fold cardboard display board can be purchased from an art & crafts supply store.

The hydrogel crystals can be purchased either locally from a garden supply store or online. Fortunately the price has been coming down. Science in A Bag charges $10 plus free shipping for a pack of these crystals. They also may be ordered from www.teacherssource.com, or Nasco Science.

A hydrogel crystal (sometimes called a “Disappearing crystal,” “Water Crystal,” “Superabsorbent gel,” etc) is a long chain of molecules bonded together to form a superabsorbent polymer, that does not dissolve, but forms a gel when placed in water and is often used in garden, landscape, and farming applications as a way of retaining moisture. Instead of dissolving, these crystals absorb water, swelling to many times their original size. The crystal is made up almost entirely of water.

The hydrogels that will be used in this project are sensitive to salt concentration but not to sugar. The hydrogel polymer is in equilibrium with the water around it, but that equilibrium can be disturbed. If the ionic concentration of the solution is increased by adding salt the positive ions attach themselves to the negative sites on the polymer, effectively neutralizing the charges which causes the hydrogel to shrink in on itself releasing water and any other substance that it has absorbed, because the sugar is covalent in structural bonding it does not change the hydrogel polymer’s equilibrium.

As the young investigator will discover it is possible to use hydrogels as a drug delivery system with tea representing the drug and the hydrogel the carrier. When salt water is added to the crystals, they begin to shrink and release the encapsulated tea. This will not happen when the crystals are placed in a sugar water solution. From this observation the young investigator will be able to conclude that if hydrogel crystals are used as drug carriers a salt solution can be used as an agent to release the drug. Digital photos can be taken during the experimenting process and/or images of crystals submerged in water can be downloaded from the Science in a Bag website for free and without copyright infringement issues.

  • What is a hydrogel superabsorbent polymer crystal?
  • What is a drug delivery system?
  • Why would a hydrogel crystal be consider as a possibly drug delivery medium?
  • Which of the two tested compounds (sugar or salt) can be used as a tea releasing agent?
  • Why is a releasing agent needed in a drug delivery system?

Hydrogel crystal,crystal, polymer, control, drug delivery system, and superabsorbent polymer

This science fair project determines which of two chemical agents can be used to release the drug (tea) from hydrogel crystals.